Main Group Multiple Bonds for Bond Activations and Catalysis
نویسندگان
چکیده
منابع مشابه
Energetic Effects of Multiple Hydrogen Bonds. Implications for Enzymatic Catalysis
The rate enhancements obtained by enzymes often require greater than 20 kcaVmol of stabilization that is specific to the transition state. Inspection of active sites suggests that enzymes often use multiple interactions with substrate groups undergoing charge rearrangement to help provide this preferential stabilization. We have analyzed the deprotonation, in DMSO, of benzoic acids with one or ...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2020
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202002939